Pentaerythritol

From Free net encyclopedia

Image:Pentaerythritol.png Pentaerythritol is a polyol used in the fabrication of PETN, alkyd resins, varnishes, PVC stabilizers, tall oil esters, olefin antioxidants, and pentaerythritol triacrylate.


Properties and description

It is a white, crystalline odorless solid, with melting point 260.5 °C and boiling point 276 °C at 30 mm Hg. It is also known under names Hercules P 6, monopentaerythritol, tetramethylolmethane, THME, PETP, pentaerythrite, Pentek.

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Preparation

It can be prepared by condensation of acetaldehyde and formaldehyde in a basic environment. The process occurs by successive aldol condensations followed a Cannizaro reaction. The result contains dipentaerythritol and tripentaerythritol as impurities.

CH3CHO + 4 CH2O + 1/2 Ca(OH)2 -> C(CH2OH)4 + 1/2 (HCOO)2Ca

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